Multilevel Heterogeneous Interfaces Enhanced Polarization Loss of 3D-Printed Graphene/NiCoO2/Selenides Aerogels for Boosting Electromagnetic Energy Dissipation.

Heterointerface engineering is an attractive approach to modulating electromagnetic (EM) parameters and EM wave absorption performance. However, the weak interfacial interactions and poor impedance matching would lead to unsatisfactory EM absorption performance due to the limitation of the construction materials and design strategies. Herein, multilevel heterointerface engineering is proposed by in situ growing nanosheet-like NiCoO2 and selenides with abundant interface structures on 3D-printed graphene aerogel (GA) skeletons, which strengthens the interfacial effect and improves the dielectric polarization loss. Benefiting from the features of substantially enhanced polarization loss and optimized impedance matching, the graphene/S-NiCoO2/selenides (G/S-NCO/Se) have achieved brilliant EM wave absorption performance with a strong reflection loss (RL) value of -60.7 dB and a broad effective absorption bandwidth (EAB) of 8 GHz, which is about six times greater than that of the graphene aerogel (-9.8 dB). Moreover, it is further confirmed by charge density differences and off-axis electron holography that a large amount of polarized charge accumulates at the interface, leading to significant polarization relaxation behaviors. This work provides a deep understanding of the effect of a multilevel heterogeneous interface on dielectric polarization loss, which injects a fresh and infinite vitality for designing high-efficiency EM wave absorbers.

Manipulation of Impedance Matching toward 3D-Printed Lightweight and Stiff MXene-Based Aerogels for Consecutive Multiband Tunable Electromagnetic Wave Absorption.

Highly conductive MXene material exhibits outstanding dissipation capability of electromagnetic (EM) waves. However, the interfacial impedance mismatch due to high reflectivity restricts the application of MXene-based EM wave absorbing materials. Herein, a direct ink writing (DIW) 3D printing strategy to construct lightweight and stiff MXene/graphene oxide aerogels (SMGAs) with controllable fret architecture is demonstrated, exhibiting tunable EM wave absorption properties by manipulating impedance matching. Noteworthy, the maximum reflection loss variation value (ΔRL) of SMGAs is -61.2 dB by accurately modulating the width of the fret architecture. The effective absorption region (fE) of SMGAs exhibits consecutive multiband tunability, and the broadest tunable fE (Δf) is 14.05 GHz, which could be continuously tuned in the whole C- (4-8 GHz), X- (8-12 GHz), and Ku-bands (12-18 GHz). Importantly, the hierarchical structures and the orderly stacking of filaments endow lightweight SMGAs (0.024 g cm-3) with a surprising compression resistance, which can withstand 36 000 times its own weight without obvious deformation. Finite element analysis (FEA) further indicates that the hierarchical structure facilitates stress dispersion. The strategy developed here provides a method for fabricating tunable MXene-based EM wave absorbers that are lightweight and stiff.

Comprehensive evaluation of cobalt incorporated cryptomelane-type manganese oxide molecular sieve as an efficient adsorbent for enhanced removal of europium from wastewater systems.

Extraction of radionuclide contaminants from wastewater systems has recently drawn widespread attention, and then developing a novel and green extracting technology has also become an enormous challenge. Herein, a facile hydrothermal method was employed to fabricate cobalt-incorporated cryptomelane-type manganese oxide molecular sieve (Co-OMS-2) for extraction Eu(III) from wastewater under diverse experimental conditions. All kinds of characterized techniques, such as SEM, TEM, XRD, FTIR, BET, EDS and XPS had verified the qualified synthesis process and splendid structural features of the Co-OMS-2. The maximum adsorption capacity of Co-OMS-2 was 7.62 × 10-4 mol/g for Eu(III) at 298 K, which was superior than primarily traditional materials reported previous literatures. The high adsorption capacity of Eu(III) onto Co-OMS-2 was primarily attributed to high specific surface area and abundant surface functional groups, and the interactions were mainly contributed to strong surface complexation and electrostatic attraction. Under the condition of low pH, the outer-sphere surface complexation and cation exchange were primary mechanisms to Eu(III) adsorption onto Co-OMS-2 composites, while inner-sphere surface complexation was mainly assigned to Eu(III) adsorption onto Co-OMS-2 under the high pH sections. The Co-OMS-2 composite achieved equilibrium in a relatively short time, and this excellent performance was conducive to the treatment of Eu(III) under the extreme emergency conditions. In view of the extraordinary adsorption capacity and recycled reusability, the Co-OMS-2 composites can be as prospective adsorbents adopted for the extraction of Eu(III) in real wastewater management.